期刊
MACROMOLECULAR SYMPOSIA
卷 242, 期 -, 页码 19-24出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/masy.200651004
关键词
foams; High Internal Phase Emulsion (HIPE); macroporous polymers; radical polymerisation; structure
We present new evidence that the formation of pore throats (windows) or pore interconnects in polymerised High internal Phase Emulsions (polyHIPEs) is most likely due to a mechanical action exerted during the post-synthesis processing of the porous polymer monolith. We would like to invite researchers interested in this field to reopen the discussion on the mechanism which lead to the formation of pore throats during the polymerisation of concentrated emulsion templates.
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