期刊
NEW JOURNAL OF CHEMISTRY
卷 30, 期 10, 页码 1397-1402出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b605958a
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We describe the synthesis and characterization, by single crystal X-ray analysis, of a 1D heteroditopic self-complementary tecton for halogen bonding. It was designed to also incorporate double bonds and to possess heteropolar pi - pi stacking groups in order to carefully control its supramolecular organization in the solid state. As a result of this supramolecular control, by UV irradiation in the solid state the compound dimerizes forming a 2D heterotetratopic self-complementary tecton tailored to halogen bonding based self-assembly. This 2D tecton crystallizes clathrating chloroform molecules.
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