The cocrystallization of 4,4'-dihydroxybenzophenone and 1,2-bis(4-pyridyl) ethylene under hydrothermal condition provides 1 : 1 adduct, which has been found to present three polymorphs 1, 2 and 3 with space group P2/c, Pca2(1) and C2/c, respectively. 4,4'-Dihydroxybenzophenone in these three compounds adopts different conformations, but they have a similar layer structure, in which 4,4'-dihydroxybenzophenone molecules are connected by 1,2-bis(4-pyridyl)-ethylene into a 1-D chain through O-H center dot center dot center dot N hydrogen bonds and C - H center dot center dot center dot O weak hydrogen bonds between adjacent 4,4'-dihydroxybenzophenone from neighboring chains further link these chains into a 2-D layer. Compound 3 has higher density than 1 and 2 due to significant pi - pi interactions between phenyl rings from adjacent layers.
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