期刊
JOURNAL OF FLUORINE CHEMISTRY
卷 128, 期 4, 页码 353-368出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2006.11.006
关键词
sol-gel-synthesis; nano-structured metal fluorides; cataylsis; Lewis acidity; optical properties
This review summarises the progress, achieved in the last 5 years, in the field of synthesis of nano-structured metal fluorides. The main focus is laid on the non-aqueous sol-gel-synthesis, which is opening a wide window toward nanoscopic metal fluorides with properties remarkably different from that of crystalline metal fluorides. Based on examples of binary as well as complex metal fluorides prepared via this new sol-gel-route it will be shown how the physical properties of nanoscopic compounds deviate from their macroscopic counterparts. (C) 2006 Elsevier B.V. All rights reserved.
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