期刊
ORGANIC PROCESS RESEARCH & DEVELOPMENT
卷 11, 期 1, 页码 105-113出版社
AMER CHEMICAL SOC
DOI: 10.1021/op0680082
关键词
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Solution chemistry is carried out in solvents, that is in liquids under the conditions of application, which can exert a considerable influence on the properties of the dissolved solute species. A short historical overview on the influence of solvents on chemical processes (equilibria, reaction rates) and physical processes (absorption spectra, crystallization) is presented. The term solvent polarity is discussed, and a solvatochromic parameter for its empirical determination is mentioned. A classification of solvents according to their chemical bonds is given, with special attention to supercritical fluids, fluorous solvents, and room temperature ionic liquids as promising new reaction media.
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