期刊
JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA
卷 203, 期 -, 页码 8-13出版社
ELSEVIER SCIENCE BV
DOI: 10.1016/j.elspec.2015.05.003
关键词
X-ray photoemission; HAXPES; Transition metal oxides
类别
资金
- Italian Ministry of Research
We present the Is X-ray photoemission spectrum of alpha-Fe2O3 in comparison with its 2p photoemission spectrum. We show that in case of transition metal oxides, because the 1s core hole is not affected by core hole spin-orbit coupling and almost not affected by core-valence multiplet effects, the Fe 1s spectrum and the complementary charge transfer multiplet calculations allow for an accurate determination of the charge transfer parameters. The consistency of the obtained parameters for the 1s photoemission was confirmed with 2p photoemission calculations and compared to 2p experimental photoemission spectra. (C) 2015 Elsevier B.V. All rights reserved.
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