期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 2, 期 3, 页码 403-410出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200600391
关键词
alcohols; amination; amines; ruthenium; transfer hydrogenation
The N-alkylation of amines in the presence of different ruthenium catalysts generated in situ was investigated. Among the various catalysts tested, the combination of [Ru-3(CO)(12)] and N-phenyl-2-(dicyclohexylphosphanyl)pyrrole showed the best performance. By applying this novel catalyst, a variety of functionalized alcohols and amines were converted into the corresponding secondary amines in high yield.
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