期刊
JOURNAL OF THE SERBIAN CHEMICAL SOCIETY
卷 72, 期 12, 页码 1363-1367出版社
SERBIAN CHEMICAL SOC
DOI: 10.2298/JSC0712363M
关键词
adsorption; thermodynamic parameters; correct calculation
The Langmuir and Freundlich isotherm equations have been widely used for interpreting various adsorption processes. There are, however, many serious mistakes in the literature in determination or calculation of thermodynamic parameters, especially in the determination of the change in the free energy of adsorption using Langmuir, Freundlich and Henry constants. Many authors used these constants for the determination of Delta G expressed instead of dimensionless in some concentration units (for example: 1 mol(-1), 1 g(-1), ml mg(-1), etc.).
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