期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 2, 期 3, 页码 411-415出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.200600383
关键词
alcohols; aldehydes; homogeneous catalysis; oxidation; ruthenium
In the presence of [Ru(terpyridine)(2,6-pyridinedicarboxylate)], aliphatic and benzylic alcohols are oxidized to the corresponding aldehydes or ketones with high selectivity by using hydrogen peroxide as the oxidant. There is no need for the addition of co-catalysts or organic solvents. By applying an optimized reaction protocol, high catalyst productivity (turnover number>10000) and activity (turnover frequency up to 14800 h(-1)) has been achieved.
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