期刊
AUSTRALIAN JOURNAL OF CHEMISTRY
卷 60, 期 6, 页码 396-399出版社
CSIRO PUBLISHING
DOI: 10.1071/CH07077
关键词
-
Hyperbranched copolymers of N-isopropylacrylamide (NIPAM) and styrene were prepared by reversible addition-fragmentation chain transfer ( RAFT) polymerization in the presence of a novel acryloyl trithiocarbonate, namely 1-[3-(2-methyl- 2-dodecylsulfanylthiocarbonylsulfanylpropionyloxy) propyl]-1H-[ 1,2,3] triazol-4-ylmethyl acrylate. By employing an example of 'click chemistry', we were able to prepare the vinyl RAFT chain transfer agent (CTA) by copper-catalyzed 1,3- dipolar cycloaddition of an azido-functionalized trithiocarbonate and propargyl acrylate. The resulting CTA facilitated the preparation of highly branched poly( N-isopropylacrylamide) ( PNIPAM) and polystyrene. Interestingly, the branched PNIPAM demonstrated a reduced lower critical solution temperature (LCST) of 25 degrees C as opposed to the conventional value of 32 degrees C expected for linear PNIPAM, an effect attributed to increased contribution of hydrophobic dodecyl trithiocarbonate end groups.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据