期刊
COORDINATION CHEMISTRY REVIEWS
卷 251, 期 7-8, 页码 925-935出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2006.09.009
关键词
hydrogen storage materials; lithium nitride; ammonia borane; zeolites; carbon nanotubes
This review surveys the state of the art in non-hydride hydrogen storage materials composed of the elements B, C, N, O, Si, and Al. In the nitrogen-based systems Li3N and NH3BH3 hydrogen is chemically bound in the formal oxidation states +1 and -1, whereas carbon nanotubes and aluminosilicate-based zeolites adsorb or encapsulate molecular H-2. The advantages and drawbacks of each system are discussed, and comparisons between them are made where appropriate. (c) 2006 Elsevier B.V. All rights reserved.
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