期刊
COORDINATION CHEMISTRY REVIEWS
卷 251, 期 5-6, 页码 726-764出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2006.07.017
关键词
N-heterocyclic carbenes; homogeneous ruthenium catalysts; supported ruthenium catalysts; RCM mechanism
A detailed overview on the synthesis of four-, five- and six-membered, saturated and unsaturated N-heterocyclic carbenes used in the preparation of their corresponding ruthenium complexes (Grubbs' second-generation, Fischer-type, Hoveyda-Grubbs, homo and hetero-bimetallic) is presented both in solution and on solid support. The catalytic activity of the different complexes in ruthenium-catalyzed metathesis reaction is compared and explained by their structural features. (c) 2006 Elsevier B.V. All rights reserved.
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