期刊
KOBUNSHI RONBUNSHU
卷 64, 期 10, 页码 607-616出版社
SOC POLYMER SCIENCE JAPAN
DOI: 10.1295/koron.64.607
关键词
supramolecular chemistry; ring-opening polymerization; cyclodextrin; lactone; lactide; polyester
Cyclodextrins (CDs) were found to initiate ring-opening polymerizations of lactones and lactides selectively to give polyesters in high yields. The order of the polymer yield of beta-butyrolactone with CDs is alpha-CD congruent to beta-CD >>gamma-CD > no CD, while the order of the polymer yield of delta-valerolactone (delta-VL) is beta-CD >alpha-CD >>gamma-CD > no CD. The yields of the polyesters depend on the cavity size of CDs and on the structures of lactones, indicating that the reaction took place via inclusion of lactones in the CD cavity. The beta-CD-adamantane inclusion complex did not show any polymerization activity for delta-VL under the same conditions because adamantane strongly inhibits the formation of the inclusion complex between,beta-CD and delta-VL. The included monomer in the CD cavity is activated by the formation of hydrogen bonds between the hydroxyl group of CDs and the carbonyl oxygen of monomers in the initiation step, which was observed by FT-IR spectroscopy. The products were found to be a polymer chain attached to the C-2-hydroxyl group of a single glucopyranose unit of CD via an ester bond. The lactones are activated by the other remaining secondary hydroxyl groups to give the propagation step by way of insertions of monomers between CD and the polymer chain. The initiation and the propagation steps of the polymerization of lactones by CDs were observed by solid state C-13 NMR techniques.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据