期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 736, 期 -, 页码 127-131出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2014.11.007
关键词
S-TiO2 composite; Cathode materials; Lithium/sulfur batteries
资金
- Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry [[2010]609]
- International Science and Technology Cooperation Plan, Science and Technology Bureau of Changchun City [11GH05]
TiO2 nanofibers were prepared by improved electrospinning technique and subsequent thermal treatment. The as-prepared TiO2 nanofibers possess anatase-rutile mischcrystal structure. Sulfur was mixed with the TiO2 nanofibers to form S-TiO2 composite by a melt diffusion process. The S-TiO2 composite displays more excellent discharge capacity retention of 58% after 50 cycles compared to pure S, and the discharge capacity is 530 mAh g(-1) after 50 cycles, which is ascribed to the adsorption of lithium polysulfide by TiO2. (C) 2014 Elsevier B.V. All rights reserved.
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