期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 17, 期 1, 页码 91-103出版社
SPRINGER
DOI: 10.1007/s10904-006-9075-2
关键词
conjugated polymer; metallopolymer; organic/inorganic hybrid material; organometallic; polymer; poly(p-phenylene ethynylene); poly(p-xylylene); PPE; PPX; processing; supramolecular polymerization; transition metal
The self-assembly polymerization of ditopic macromolecules via metal-ligand binding is a facile route for the preparation of metallo-supramolecular polymers (MSPs). We herein review our recent work focused on the synthesis and investigation of metallo-supramolecular polymers based on 2,6-bis(1'-methylbenzimidazolyl)pyridine endcapped poly(p-phenylene ethynylene) and poly(p-xylene) macromonomers. These materials are readily solution-processable and display appreciable mechanical properties as well as other attractive properties such as specific opto/electrical functions or high thermal stability. Our work illustrates that metallosupramolecular polymerization offers an attractive approach to assemble high-molecular-weight macromolecules from well-defined, easy to process precursors. Variation of the ditopic ligands and metal ions allows one to easily tailor the desired properties.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据