期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 741, 期 -, 页码 56-63出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2015.01.015
关键词
Direct alcohol fuel cell; Palladium; Titanium dioxide; Multiwall carbon nanotube; Electrocatalyst
资金
- Foundation of State Key Laboratory of Pollution Control and Resource Reuse of China
- Natural Science Foundation of China [51308282]
- foundation research project of Jiangsu province (Natural Science Foundation of China) - Youth Fund Project [BK20130574]
A Pd/TiO2-multi-walled carbon nanotubes (MWCNTs) catalyst has been synthesized for use in direct alcohol fuel cells using an in situ chemical method. TiO2 pretreated with HNO3 and HF was applied as a support material between the Pd nanoparticles and MWCNTs template. Transmission electron microscopy, X-ray diffraction, and X-ray photoelectron spectroscopy analysis indicated that the metallic-state Pd nanoparticles were uniformly dispersed onto the TiO2 particles anchored onto the MWCNTs. Electrochemical characterizations using cyclic voltammetry and chronoamperometry measurements demonstrated that the Pd/TiO2-MWCNTs catalyst showed higher electro-catalytic activity, durability, and stability for methanol, ethanol, and isopropanol oxidation than the Pd/MWCNTs catalyst. Furthermore, the electro-catalytic activity and durability for alcohols was of the order ethanol >= methanol >= isopropanol. The effect of the scan rate was also studied. The results indicated that the alcohol oxidation process on the Pd/TiO2-MWCNTs modified electrode was irreversible and controlled by the diffusion of the alcohols. Taken together, these results demonstrated that the Pd/TiO2-MWCNTs electrode has good potential for significant application in fuel molecular oxidation. (C) 2015 Elsevier B.V. All rights reserved.
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