期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 737, 期 -, 页码 37-45出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2014.09.029
关键词
EIS; Titanium oxide; Nanotube array; Polypyrrole; PEDOT
The model suggested by Deslouis and co-workers [14] for describing the behavior of polypyrrole deposited on a metallic substrate is here used for conducting polymers deposited on a nanostructured 3D semiconducting substrate. Impedance measurements were performed on a titanium oxide nanotubular array in the presence of two types of conducting polymers: polypyrrole and poly(3,4-ethylenedioxythiophene), highlighting the modification of the semiconducting properties of the substrate induced by the polymer deposition. The model is shown to be particularly well adapted for the PEDOT/TiO2 hybrid structure, providing a valuable tool for characterizing the interaction between the conducting polymer and the semiconducting substrate. (C) 2014 Elsevier B.V. All rights reserved.
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