期刊
RESEARCH ON CHEMICAL INTERMEDIATES
卷 33, 期 3-5, 页码 297-309出版社
SPRINGER
DOI: 10.1163/156856707779238595
关键词
photocatalysis; semiconductor; alpha-cyano-homoallylamines; H-1-NMR; C-13-NMR
alpha-Cyano-homoallylamines are synthesised in moderate yields by the photocatalysed linear addition of olefins to Ph(CN)C=NPh in the presence of silica-supported cadmium sulphide. Band edge positions of cadmium sulphide and the rate and diastereoselectivity of this radical C-C coupling reaction are not significantly changed when the semiconductor is supported onto cellulose. The latter result is in accordance with the absence of covalent semiconductor-support interactions.
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