期刊
ISRAEL JOURNAL OF CHEMISTRY
卷 47, 期 1, 页码 11-16出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1560/IJC.47.1.11
关键词
-
The molecular dynamics of methylamine, CH3NH2, was investigated via vibrationally mediated photodissociation. It was found that the similar to 243.1 nm photolysis of initially excited N-H and C-H fundamental stretches and combinations and overtones of methyl deformation yields H photofragments. Surprisingly, the deformations promote the H atom release more effectively, implying mode-dependent enhancement of photodissociation in a relatively large molecule with a torsional degree of freedom. The H Doppler profiles correspond to low translational energies, supporting the dominant non-adiabatic N-H dissociation channel.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据