We have performed high-resolution angle-resolved photoemission spectroscopy on YBa2Cu3O7-delta (Y123; delta=0.06; T-c=92 K). By accurately determining the Fermi surface and energy band dispersion, we solve long-standing controversial issues as to the anomalous electronic states of Y-based high-T-c cuprates. We unambiguously identified surface-bilayer-derived bonding and antibonding bands, together with their bulk counterparts. The surface bands are highly overdoped (hole concentration x=0.29), showing no evidence for the gap opening or the dispersion anomaly in the antinodal region, while the bulk bands show a clear d(x)(2)-y(2)-wave superconducting gap and the Bogoliubov quasiparticlelike behavior with a characteristic energy scale of 50-60 meV indicative of a strong electron-boson coupling in the superconducting state. All these results suggest that the metallic and superconducting states coexist at the adjacent bilayer of Y123 surface.
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