期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 43, 页码 4441-4449出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b707737h
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资金
- NIGMS NIH HHS [R01 GM063755, R01 GM063755-09] Funding Source: Medline
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM063755] Funding Source: NIH RePORTER
Nickel-catalysed reductive coupling reactions of alkynes have emerged as powerful synthetic tools for the selective preparation of functionalized alkenes. One of the greatest challenges associated with these transformations is control of regioselectivity. Recent work from our laboratory has provided an improved understanding of several of the factors governing regioselectivity in these reactions, and related studies have revealed that the reaction mechanism can differ substantially depending on the ligand employed. A discussion of stereoselective transformations and novel applications of nickel catalysis in coupling reactions of alkynes is also included.
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