期刊
CHEMICAL COMMUNICATIONS
卷 -, 期 37, 页码 3868-3870出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b706926j
关键词
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In a computational investigation, dinuclear and tetranuclear copper acetylide complexes display both superior stability and higher reactivity in the CuAAC reaction than do mononuclear complexes due to favored dicopper( I, III) mu-alkenylidene fragments, instead of ring strain in a Cu=C=C intermediate.
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