期刊
CHEMOSPHERE
卷 66, 期 3, 页码 435-443出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.chemosphere.2006.06.031
关键词
creosote; bioassay-directed fractionation; N-heterocyclics; polycyclic aromatic hydrocarbons; groundwater; bioluminescence inhibition
Despite the fact that creosote mainly consists of polycyclic aromatic hydrocarbons (PAHs), more polar compounds like phenolics, benzenes and N-, S-, O-heterocyclics dominate the groundwater downstream from creosote-contaminated sites. In this study, bioassay-directed fractionation, combined with fullscan GC-MS, identified organic toxicants in creosote-contaminated groundwater. An organic extract of creosote-contaminated groundwater was fractionated on a polar silica column using high performance liquid chromatography (HPLC), and the toxicity of the fractions was measured by the Microtoxo-bioassay. PAHs, which comprise up to 85% of pure creosote, accounted for only about 13% of total toxicity in the creosote-contaminated groundwater, while methylated benzenes, phenolics and N-heterocyclics accounted for ca. 80% of the measured toxicity. The fraction containing alkylated quinolines was the most toxic single fraction, accounting for 26% of the total measured toxicity. The results imply that focus on PAHs may underestimate risks associated with creosote-contaminated groundwater, and that environmental risk assessment should focus to a higher degree on substituted PAHs and phenolics because they are more toxic than the unsubstituted ones. Additionally, benzenes and N-heterocyclics (e.g., alkylated quinolines) should be assessed. (c) 2006 Elsevier Ltd. All rights reserved.
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