期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 27, 期 13-15, 页码 3951-3954出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2007.02.073
关键词
perovskites; softmagnetic; sintering; ferroelectric property; magnetic property
Dielectric and magnetic properties of the xBiFeO(3) yDyFeO(3)-zBaTiO(3) solid solution ceramics at high temperature range of RT similar to 600 degrees C have been characterized. For the more detailed understandings of the multiferroic property, the relation between the crystal structure transition, magnetic transition. dielectric transition with increasing temperature have been analyzed. Residual magnetization M-r under the low and high applied magnetic fields (H = 20 Oe. 8 kOe) and the dielectric properties, epsilon(r), and tan 3, with varying measuring frequency and temperature have been characterized using the vibrating sample magnetometer and LCR meter, respectively. The neutron diffraction data has been collected at the temperature range of RT similar to 800 degrees C. The low DyFeO3 concentration samples (y = 0, 0.025) show the magnetic transitions at temperature range of 410-430 degrees C, while the high DyFeO3 samples (y >= 0.05) show the additional transition at 250-290 degrees C. The magnetic transition at 410-430 degrees C corresponds to the crystal structural transition to the tetragonal P4mm from the rhombohedral R-3c. at which the BiFeO3 and the DyFeO3 samples lose their anti ferro magnetic ordering. (c) 2007 Elsevier Ltd. All rights reserved.
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