期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 13, 期 10, 页码 2929-2936出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.200601224
关键词
gold; micelles; nanorods; surface plasmon resonance; surfactants
Gold nanorods were prepared in high yields by using a one-step seed-mediated process in aqueous cetyltripropylammonium bromide (CTPAB) and cetyltributylammonium bromide (CTBAB) solutions in the presence of silver nitrate. ne diameters of the nanorods range from 3 to 11 nm, their lengths are in the range of 1.5 to 350 nm, and their aspect ratios are in the range of 2 to 70. The diamers of the Au nanorods obtained from one growth batch in CTPAB solutions decrease as their lengths increase, and their volumes decrease as the aspect ratios increase. The diameters of the Au nanorods obtained from one growth batch in CTBAB solutions first decrease and then slightly increase as their lengths increase, and their volumes increase as the aspect ratios increase. These An nanorods are single-crystalline and are seen to be oriented in either the [100] or [110] direction under transmission electron microscopy imaging, irrespective of their sizes. To the best of our knowledge, this is the first report of the preparation by using wet-chemistry methods of single-crystalline Au nanorods with aspect ratios larger than 15.
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