期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 5, 期 7, 页码 1031-1038出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b618178c
关键词
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Lantibiotics such as nisin are active against most Gram-positive bacteria and constitute an important class of antibacterial agents. These ribosomally synthesized peptides contain either one or both of the unusual amino acids meso-lanthionine (m-Lan) or beta-methyllanthionine (beta-MeLan). Nucleophilic ring opening of sulfamidates allows facile preparation of stereochemically pure derivatives of m-Lan and beta-MeLan with orthogonal protection for solid phase synthesis of lantibiotic analogues.
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