期刊
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
卷 9, 期 44, 页码 5897-5901出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b712798g
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Hyper. ne structures arising from the couplings of the nuclear spin angular momentum of O-17 (I = 5/2) with the end over end rotation of several metal-containing diatomic monoxides have been observed using a Fourier transform microwave spectrometer. The molecules have been produced by reacting O-17(2) with laser ablated metal atoms. The oxygen-17 nuclear quadrupole coupling constants have been determined for the title molecules and are interpreted in terms of a simple Townes-Dailey model. Also, the oxygen-17 nuclear spin-rotation constants have been determined and used to calculate the oxygen-17 shieldings for each molecule.
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