期刊
JOURNAL OF MATERIALS CHEMISTRY
卷 17, 期 14, 页码 1421-1426出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b616381e
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New prototype semiconductor materials based on dibenzothiophene (DBT) derivatives were successfully synthesized by a convergent approach using palladium catalyzed Stille coupling reactions. Thermogravimetric analysis, UV-vis spectra and electrochemistry results indicated these materials had good thermal and photooxidation stability. X-Ray diffraction measurements of the vacuum-evaporated films showed enhanced crystalline order with increasing substrate deposition temperature. The ordered vacuum-evaporated films with charge carrier mobility as high as 7.7 x 10(-2) cm(2) V-1 s(-1) and an on/off ratio of nearly 1 x 10(7) had been achieved with 3,7-bis(5'-hexyl-thiophen-2'-yl)-dibenzothiophene (3,7-DHTDBTT). These results suggest that the 3,7-substituted DBT system is a good prototype for new type organic semiconductors and will play a more important role in organic semiconductors.
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