期刊
JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 692, 期 1-3, 页码 375-381出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2006.08.053
关键词
palladium catalyst; allenes; Grignard reagent; chlorosilanes; alkyl halides
Allenes react with Grignard reagents and chlorosilanes in the presence of a palladium catalyst giving rise to carbosilylated products bearing carbon groups from Grignard reagents at the central carbon and silyl groups at the terminal carbon. When alkyl halides were used instead of chlorosilanes, the corresponding alkylated products were obtained. (c) 2006 Elsevier B.V. All rights reserved.
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