期刊
ORGANIC & BIOMOLECULAR CHEMISTRY
卷 5, 期 24, 页码 3951-3955出版社
ROYAL SOC CHEMISTRY
DOI: 10.1039/b714765a
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Comparative study of electrochemical redox behaviour of five different nitroxyl radicals leads to the direct correlation between one-electron redox potentials and group electronegativity of the beta-substituent on the ring. beta-Substituents with an electron-donating effect caused a negative shift in the one-electron oxidation and one-electron reduction potentials of the nitroxyl radicals. In a similar aspect, beta-substituents with an electron-withdrawing effect behaved oppositely.
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