4.7 Article

A kinetic study of the thermal degradation of 3-methylaminopropylamine inside AlPO4-21

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JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
卷 87, 期 2, 页码 337-341

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SPRINGER
DOI: 10.1007/s10973-005-7382-4

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AlPO4-21; kinetic parameters; open-framework; TG; thermal decomposition

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Kinetics of the thermal decomposition of 3-methylaminopropylamine which was used as a structure-directing agent in the synthesis of AlPO4-21 has been studied under isothermal and non-isothermal conditions. The decomposition is a single-step reaction occurring in the 573-663 K range. It is a phase-boundary-controlled process, described by the 'F2/3, R3' kinetic model. The activation energy values obtained under the non-isothermal and isothermal conditions lie in the 173-151 kJ mol(-1) range.

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