Measurement of natural radioactivity in bottled drinking water in Pakistan and consequent dose estimates

Natural radioactivity was determined in 11 different brands of commonly sold bottled drinking water in the federal capital Islamabad and Rawalpindi city of Pakistan using gamma spectrometry technique. Mean concentrations of Ra-226, Th-232 and K-40 were found to be 11.3 +/- 2.3, 5.2 +/- 0.4 and 140.9 +/- 30.6 mBq l(-1), respectively. The annual cumulative effective doses due to all three natural radionuclides for different age groups of 1-5 y, 5-10 y, 10-15 y and adults (>= 8 y) were estimated to be 4.0, 3.4, 3.1 and 4.1 mu Sv y(-1), respectively. Among the three natural radionuclides, annual effective doses for all age groups from Ra-226 were significant. Children in the age group of 1-5 y appeared to be at risk with respect to the annual effective doses from Ra-226 as compared to the other age groups. Results obtained in this study are compared with the reported values from other countries of the world and it was observed that measured activity concentrations of three natural radionuclides in the bottled drinking water were lower than these values. Annual estimated effective doses for all four age groups from the intake of natural radionuclides in bottled drinking water were also found below the World Health Organisation (WHO) recommended limit of 0.1 mSv y(-1) as well as the average radiation dose of 0.29 mSv y(-1) received per head worldwide due to ingestion of natural radionuclides assessed by UNSCEAR (2000).