4.1 Article

Synthesis and crystal structure of [Pb(trz)(tfpb)(H2O)]: a lead(II) complex containing 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 4,4,4-trifluoro-1-phenyl-1,3-butandionate

期刊

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200600341

关键词

lead; intermolecular interactions; crystal structure

向作者/读者索取更多资源

[Pb(trz)(tfpb)(H2O)] (1) (trz and tfpb are the abbreviations of 2,4,6-tris(2-pyridyl)-1,3,5-triazine and 4,4,4-trifluoro-1-phenyl-1,3-butandionate, respectively) have been synthesized and characterized by elemental analysis and IR, H-1 NMR, spectroscopy. The single-crystal structure of 1 shows the coordination number of the Pb2+ ions is eight with three N-donor atoms from a trz ligand and four O-donors from the dionate ligand and one molecule of water. The supramolecular features in this complex are guided by lone pair activity and control of strong hydrogen bonds, weak directional intermolecular interactions and aromatic pi-pi stacking interactions.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.1
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据