期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 349, 期 6, 页码 781-795出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.200600458
关键词
alcohols; asymmetric catalysis; hydrosilylation; phosphane ligands; secondary interactions
A structure-activity survey of monophosphane ligands used in the asymmetric palladium-catalysed hydrosilylation reaction of olefins is presented and used to assess the role of secondary interactions on catalyst activity and selectivity.
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