期刊
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY
卷 52, 期 1, 页码 42-45出版社
MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S0036023607010081
关键词
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The copper(II) compounds [CuL](NO3)(2) center dot H2O (I), [CuL](ClO4)(2) center dot H2O (II), CuLCl2 center dot 3H(2)O (III), and CuLBr2 center dot 4H(2)O (IV), where L is a chiral dioxatetraazamacrocyclic ligand based on the natural monoterpene (+)-3-carene, have been synthesized. According to IR and EPR spectroscopy, L acts as a tetradentate chelating ligand coordinated through the N atoms of the NH and C=N groups. The NO3- anions in I and the ClO4- anions in II are outer-sphere. I and II have a planar coordination core CuN4, III has a CuN4ClO coordination core, and IV has a CuN4Br2 coordination core.
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