期刊
CANADIAN JOURNAL OF CHEMISTRY
卷 92, 期 8, 页码 688-694出版社
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/cjc-2013-0341
关键词
F-BODIPY; dipyrrin reduction; dipyrromethane formation; microwave-assisted
资金
- Natural Sciences and Engineering Research Council of Canada
The reduction of BODIPYs and dipyrrins to dipyrromethanes, via a reaction involving ethylene glycol and sodium methoxide, is reported. When benzyl alcohol is used in place of ethylene glycol, the addition of 2,4-dinitrophenylhydrazine to the reaction mixture after microwave irradiation results in the production of 1-benzylidene-2-(2,4-dinitrophenyl) hydrazone, indicating concomitant production of aldehyde alongside the dipyrromethane.
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