Electrocatalysis and photoelectrochemistry based on functional nanomaterials

Catalysis plays a key role in chemical production, energy processing, air purification, water treatment, food processing, and the life sciences. Nanostructured materials with high surface areas and some unique properties have received widespread interest in electrocatalysis and photocatalysis. Recently, the author's research team has designed and studied a variety of novel functional nanomaterials. This review article is derived from the author's 2013 Canadian Catalysis Lectureship Award Lecture and focuses primarily on the electrocatalytic activities of platinum-and palladium-based nanomaterials and the development of TiO2-based nanostructured photocatalysts. Palladium possesses several exceptional properties that may enable promising applications in hydrogen detection, purification, and storage. The significant roles of palladium-based nanomaterials in facilitating the growth of a hydrogen economy are addressed. As platinum-based catalysts are vital to the development of fuel cells and sensors, the design of high-performance platinum-based electrocatalysts is highlighted. Additionally, TiO2 is considered to be one of the most promising photocatalysts due to its nontoxicity, high stability, and cost effectiveness. The modification of TiO2 nanomaterials to achieve visible light response is discussed as well. It is anticipated that the development of advanced functional nanostructured catalysts will further improve the efficiency and reduce the cost of electrochemical and photochemical processes, making them more attractive in addressing the pressing global energy and environmental issues.