期刊
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
卷 90, 期 1, 页码 138-144出版社
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/V11-133
关键词
magnetic nanoparticles; reducing agent; supported Pd catalyst; reductive homocoupling; aryl halides
资金
- National Science Foundation of China [20225318, 20325208, 20902007]
- National Science and Technology Major Project Development of Novel Vaccines, Antibodies and Therapeutic Agents against Influenza Infection [2009ZX10004-016]
- National Basic Research Program of China (973 Program [2010CB833201]
- Shenzhen Basic Research Program [JC200903160352A, JC201005260097A, CXB201005260053A]
- Engineering and Physical Sciences Research Council (EPSRC)
- Royal Society of Chemistry
A palladium pincer catalyst grafted onto the surface of magnetic nanoparticles (MNPs) has been developed. This material effectively catalyzes the reductive homocoupling of various aryl halide substrates, with the MNP support acting as the reducing agent. The catalyst can be recycled up to five times in the absence of additional reducing agent to give almost quantitative yields of biaryl homocoupling products. After the reducing power of the MNP has been depleted, the supported Pd complex remains an effective catalyst for Suzuki-Miyaura cross-coupling.
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