期刊
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
卷 88, 期 8, 页码 797-803出版社
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS
DOI: 10.1139/V10-029
关键词
arsine-triel (boron, aluminum, gallium) Lewis adducts
资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- Canada Research Chairs Program
- Canada Foundation for Innovation (CFI)
- Walter C. Sumner Foundation
- Nova Scotia Research and Innovation Trust Fund
- Atlantic Region Magnetic Resonance Centre
Complexes of arsine ligands (R3As, R = Me, Et, Ph) and Lewis acids of group-13 elements of the form EX3 (E = B, X = Ph, C6F5; E = Al, X = Cl, Br, I; E = Ga, X = Cl) have been isolated and characterized by X-ray crystallography, infrared spectroscopy, H-1, C-13{1H}, B-11{1H}, and Al-27 NMR spectroscopy. The compounds are compared with rare arsine-triel adducts.
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