期刊
CANADIAN JOURNAL OF CHEMICAL ENGINEERING
卷 92, 期 12, 页码 2157-2165出版社
WILEY
DOI: 10.1002/cjce.22073
关键词
catalytic hydrogenation; 3; 4-Dimethoxybenzopheone; Pd; C; 3; 4-Dimethoxybenzhydrol; kinetics
资金
- UGC under its SAP program (Centre of Advanced Studies in Chemical Engineering)
- DFAIT- Govt. of Canada
- R. T. Mody Distinguished Professor Endowment
- J. C. Bose National Fellowship of Department of Science and Technology, Govt. of India
- Science and Engineering Research Council of Canada (NSERC)
Selective hydrogenation of benzophenone to benzhydrol is industrially relevant. In the current work, selective hydrogenation of 3,4-dimethoxybenzophenone (3,4-DMBP) to 3,4-dimethoxybenzhydrol (3,4-DMBH) was investigated over 5% w/w Pd/C and 5% w/w Pt/C as catalysts in a slurry reactor. The effects of hydrogen partial pressure (0.2-1MPa), catalyst loading (2.0x10(-4) to 8.0x10(-4)g/cm(3)), initial concentration of 3,4-dimethoxybenzophenone (5.0x10(-6) to 1.5x10(-4)mol/cm(3)) and temperature (40-70 degrees C) on rate of reaction and selectivity were studied. Effect of solvent such as methanol, ethanol, 2-propanol and tetrahydrofuran (THF) was also investigated. 5% w/w Pd/C was the better catalyst with THF as the best solvent, which gave 100 % conversion and 80 % selectivity in 1h for 0.5MPa hydrogen pressure at 60 degrees C. The Langmuir-Hinshelwood-Hougen-Watson model was fitted. The intrinsic kinetics and mechanism of hydrogenation were established.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据