Controls on the spatial distribution of soil moisture and solute transport in a sloping reclamation cover

A detailed field study was conducted to map the spatial distribution of soil moisture and salt transport within a sloping clay-rich reclamation cover overlying a saline-sodic shale overburden landform. The soil moisture data suggest that: lower-slope positions are wetter in spring due to the down-slope movement of surface run-off; infiltration occurs via preferential flow paths while the ground is frozen; and, interflow occurs along the cover-shale surface when the ground thaws. Soil moisture conditions also remain wetter in lower-slope positions throughout the summer and fall. Salt transport from the shale into the overlying cover is affected predominantly by soil moisture conditions and lateral groundwater flux. Quasi one-dimensional modelling of in situ profiles of pore-water Na+ concentration demonstrate that: (i) increased soil moisture conditions in lower-slope positions accelerate salt transport into the cover through diffusion; (ii) snow melt infiltration water bypasses the soil matrix higher in the cover profile; (iii) drier conditions in the mid- and upper-slope positions limit salt transport through diffusion; (iv) advection accelerates upward salt transport in lower-slope positions; and, (v) interflow and (or) deep percolation are key mechanisms mitigating vertical salt movement in lower- and upper-slope positions.