期刊
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY
卷 46, 期 1, 页码 21-32出版社
JOHN WILEY & SONS INC
DOI: 10.1002/pola.22351
关键词
crosslinking; hydrosilylation; macroporous polymers; polyHIPE; polysiloxanes
Microcellular polysiloxane monoliths were prepared from the continuous phase of a concentrated inverse emulsion. The formulation of the material was adapted to obtain monoliths having structural properties similar to those of common poly(styrene-co-divinylbenzene) polyHIPEs. The network was generated by hydrosilylation reaction between a vinylsiloxane crosslinking agent and an oligomeric hydrogenosiloxane. The solids obtained were characterized by mercury porosimetry, nitrogen sorption, and SEM. (c) 2007 Wiley Periodicals, Inc.
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