期刊
BULLETIN OF THE KOREAN CHEMICAL SOCIETY
卷 31, 期 6, 页码 1489-1495出版社
WILEY-V C H VERLAG GMBH
DOI: 10.5012/bkcs.2010.31.6.1489
关键词
MOF materials; Ni-CPO-27; Microwave synthesis; Epoxidation; Cyclohexene
资金
- Ministry of Education, Science and Technology [KN-0942]
- international collaboration program (KICOS)
- Kongju National University
- KOFST at KRICT, Daejeon, Korea
A porous coordination solid of nickel(II) dihydroxyterephthalate has been synthesized by the microwave-assisted (MW) method. The synthesized nickel(II) dihyroxylterephthalate was designated by the general formula of[Ni-2(dhtp) (H2O)(2)]center dot 8H(2)O (where, dhtp = 2,5-dihydroxyterephthalate, denoted by Ni-DHTP). The effect of microwave-irradiation temperature and time of irradiation on the porosity and morphological changes in the solids have also been investigated. The catalytic performance of Ni-DHTP synthesized by MW method has been studied in the oxidation of cyclohexene with aqueous H2O2, which gave cyclohexene oxide as the primary product and 2-cyclohexene-l-ol as a major product.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据