期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 86, 期 7, 页码 864-869出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20130063
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资金
- Okayama University
- Adaptable and Seamless Technology Transfer Program of JST
- JGC-S Scholarship Foundation
The treatment of 6-chloroindolo[3,2-c]quinoline 6 with NaH-MeI led to methylation at N-11, forming 8, while the reaction of 6 with MeI with heating gave the corresponding 5-methylated quinolinium salt whose SNAr with water smoothly proceeded to form 5-methylindolo[3,2-c]quinolin-6-one 3b. The amination reactivity at the C-6 was assigned in the order of 6 > 11-methylated 8.
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