期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 83, 期 8, 页码 855-876出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.20090336
关键词
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资金
- MEXT [18065003, 18033011, 20686055, 18106013]
- Inoue Foundation for Science
- JCII Subsidy System for Advanced Innovation in Chemical Industry
- PF-PAC [2004G080, 2004G081, 2004G082, 2005G207, 2005G208, 2005G209, 2007G102, 2008G154, 2008G188, 2009G076, 2009G080]
- SPring-8 [2005A0451, 2005A0452, 2007B1081, 2009A1052]
- Grants-in-Aid for Scientific Research [20686055, 18106013, 18033011, 18065003] Funding Source: KAKEN
Molecular-scale design of catalytically active structures at oxide surfaces is highlighted, focusing on our recent challenges for selective heterogeneous catalysis. We found novel structural transformations of supported metal complexes on oxide surfaces and achieved unique selective catalysis for various chemical syntheses. In this account, the advanced design of supported metal-complex catalysts on oxide surfaces and the in situ characterization of their structural kinetics, which means kinetics of structural changes of catalysts themselves, under catalyst-working conditions are reviewed.
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