期刊
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
卷 82, 期 5, 页码 613-617出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.82.613
关键词
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资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [19655078]
- JSPS [17-8117, 19-8820]
- Grants-in-Aid for Scientific Research [19655078] Funding Source: KAKEN
Oriented architectures are formed on nanocrystals with incorporation of organic polymers through a biomimetic route. The composites of potassium sulfate and potassium hydrogen phthalate/poly(acrylic acid) exhibit a mosaic structure consisting of organic polymers and ca. 20 nm nanocrystals. These nanocrystalline mosaics have organic domains originating from organic polymers in nanoscopic scale and serve as a host material for the incorporation and photochemical reaction of organic molecules. Photoisomerization of azobenzene and photodimerization of coumarin are successfully demonstrated in the composite materials, indicating that the nanocrystalline mosaic has potential as a new family of host material.
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