期刊
ARKIVOC
卷 -, 期 -, 页码 205-223出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.0011.216
关键词
Organocatalysis; Michael addition; bifunctional thiourea catalysts; Cinchona alkaloids; Meldrum's acid
资金
- National Technology Agency of Finland
The asymmetric Michael addition of Meldrum's acid to nitroalkenes was studied using a novel type of Cinchona alkaloid-based bifunctional thiourea organocatalyst. The functionality of the thiourea catalysts was also probed by preparing and testing thiourea-N-methylated analogues of the well-known bis-(3,5-trifluoromethyl)phenyl-substituted catalyst.
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