期刊
ARKIVOC
卷 -, 期 -, 页码 350-359出版社
ARKAT USA INC
DOI: 10.3998/ark.5550190.0011.b28
关键词
Bioorthogonal; cyclooctyne; azides; click chemistry
A novel carboxylic acid substituted dibenzoazacyclooctyne precursor has been synthesized using a fast and innovative three-step synthesis. It can be easily converted into the corresponding alkyne through UV-irradiation. Due to its fast and regioselective reaction with azides, the alkyne is a promising agent for copper-free click chemistry. The second order reaction rate constant was determined by H-1-NMR.
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