期刊
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS
卷 75, 期 11, 页码 1149-1199出版社
INST ORGANIC CHEM AND BIOCHEM
DOI: 10.1135/cccc2010054
关键词
closo-Decaborate; Boranes; Synthesis; Derivatives; Applications
资金
- Russian Foundation for Basic Research [08-03-00463, 10-03-91331]
The review covers the fifty-year period of chemistry of the closo-decaborate anion [B10H10](2-) from the first report by Hawthorne and Pitochelli. The main attention is paid to reactions of substitution of various atoms and groups for hydrogen atoms. The general stability of the closo-decaborate cage, including its protonation, cage-opening and cage oxidation reactions, is considered as well. A review with 242 references.
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