期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 459, 期 -, 页码 136-145出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2015.08.023
关键词
Bi12O17Cl2; Poly(vinyl pyrrolidone); Photocatalysis; Rhodamine B; 2,4-Dichlorophenol; Mechanism
资金
- National Natural Science Foundation of China [21207089]
- ROCS, SEM
- Hujiang Foundation of China [B14003]
A series of novel oxygen-rich bismuth oxychloride (Bi12O17Cl2) were synthesized through a facile poly (vinyl pyrrolidone) (PVP)-assisted hydrothermal route. These obtained Bi12O17Cl2 samples were characterized by various physicochemical techniques. It was found that a proper addition amount of PVP could promote the transformation of Bi12O17Cl2 morphology from irregular clusters to three-dimensional hierarchical flower-like microspheres that were nominated as sample BP2. As-synthesized samples were subjected to a photocatalytic degradation of dye Rhodamine B (RhB) or 2,4-dichlorophenol (2,4-DCP) under visible light. Among all candidates, the sample BP2 with a hierarchical flower-like morphology showed the best degradation efficiency for RhB and 2,4-DCP. The apparent rate constant of sample BP2 in terms of degradation of RhB was nearly 5.7 and 45 times that of unmodified BP0 and N-TiO2. The enhanced photocatalytic performance could be ascribed to synergetic effects including unique hierarchical morphologies, large specific surface area, small particle size, good crystallinity, and suitable band structures. A possible mechanism of catalytic degradation was finally proposed basing upon the active species trapping experiments. (C) 2015 Elsevier Inc. All rights reserved.
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